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Academician Dai Hongjie of Stanford University reported that rechargeable Na / Cl2 or Li / Cl2 batteries can be obtained by redox between Cl2 / CL − in carbon micropores and Na / Na + or Li / Li + on Na or Li metal with high microporous carbon (ACNS) as positive electrode, aluminum trichloride (AlCl3) in SOCl2 containing fluorine additive as starting electrolyte and Na or Li as negative electrode. Reversible oxidation-reduction of Cl2 / NaCl or Cl2 / LiCl in microporous carbon can achieve rechargeability on the positive side, while thin alkali fluorine doped alkali chlorine solid electrolyte interface (SEI) is used to stabilize the negative electrode. Both are the key to rechargeable alkali metal / Cl2 battery.